Post by Andy CapFROM THE KWIK FIT SITE :-
" Nitrogen
Filling your tyres with nitrogen may seem odd but thats exactly what motor
sport and aviation professionals have been doing for years. Nitrogen is
completely safe. And by using it in a mixture with oxygen to inflate your tyres
the theory is that its possible to negate the issue of slow deflation, which is
caused by oxygen slowly infusing through the tyre wall from the atmosphere.
Having a tyre that does not deflate means you will improve fuel consumption and
will probably improve safety standards too. Its not yet standard practice but
Nitrogen could well be here to stay as a result. "
OK, I can just about make out some valid physics amongst the
bullshit.
If we assume there's no oxygen in the tyre, then an oxygen
molecule outside the tyre will see a vacuum inside the tyre.
The partial pressure of oxygen outside the tyre will be 20%
of air pressure (15 lb/sq.inch), i.e. 3 lb/sq.inch, so there
will be about 3 lb/sq.inch of pressure forcing oxygen to
diffuse in through the tyre.
Now consider the nitrogen. Assume the tyre is pumped up to, say,
30 lb/sq.inch nitrogen above air pressure, which is 45 lb/sq.inch
absolute. The partial pressure of nitrogen outside the tyre
will be 80% of 15 = 12 lb/sq.inch, so the net difference is
45 - 12 = 33 lb/sq.inch
So there's 3 lb/sq.inch of oxygen pressure outside the tyre
against 33 lb/sq.inch net of nitrogen pressure inside the tyre
(which by way of confirmation, cancels to give the 30 lb/sq.inch
observed tyre pressure). The ratio of the oxygen to nitrogen
pressures is 1:11.
Now, if the rate of diffusion of oxygen through the tyre is
more than 11 times the rate of diffusion of nitrogen through
the tyre, the pressure in the tyre will rise as more oxygen
will diffuse in, than nitrogen diffuses out.
So this boils down to the relative rate of diffusion of
Oxygen and Nitrogen through the tyre, and I don't know this
so I can only guess from now on. The two gasses are quite
similar in terms of molecule size, and I don't believe
that would cause a difference anywhere near 11:1. Oxygen
is potentially quite reactive, and there maybe some other
mechanism for getting it through the tyre if the molecule
can be pulled apart and reassembled by chemical reaction,
so it's actually the atoms diffusing through rather than
the molecule, whereas Nitrogen is less likely to have such
a mechanism, being more inert.
So it would be good to know what the mechanism at play here
really is.
If anyone has access to a nitrogen cylinder, it would be
interesting to blow up a balloon with pure nitrogen, seal,
and then see if it slowly gets bigger. (Need to cancel out
effects of size change due to temperature change.)
Diffusion through a balloon may not work same way as
diffusion through a tyre though, so it still won't
necessarily confirm or refute this theory. Also, diffusion
through the rubber may not be the primary mechanism and
certainly won't be the only mechanism for gas exchange
in/out of a tyre. Valve seals, rim seal, etc are also
potential candidates, and diffusion/leaks through these
may behave quite differently.
--
Andrew Gabriel
[email address is not usable -- followup in the newsgroup]